Structure,stability and permeation properties of NaA zeolite membranes for H2O/H2 and CH3OH/H2 separations

NaA zeolite membranes were synthesised in the secondary growth hydrothermal method based on the seeding of the inner surface of a ceramic α-alumina tube. The impacts of crystallisation time and zeolite precursor concentration (in H₂O) were investigated. The structure and stability of the prepared NaA zeolite membranes were also investigated with operating temperatures, times and pressures. The results indicate that the optimal synthesis gel molar composition was 3Na₂O: 2SiO₂: Al₂O₃: 200H₂O. This led to cubic-shaped NaA zeolite which showed good stability. The optimal NaA zeolite membrane had H₂O and CH₃OH fluxes of 2.77 and 0.19 kg/m²h, with H₂O/H₂ and CH₃OH/H₂ separation factors of ∞ and 0.09 at a temperature of 30 °C. The NaA zeolite membrane had high thermal stability, but poor separation performance at high temperature (240 °C). The results suggested that the H₂ permeation flux is significantly influenced by preferential adsorption of vapour in the NaA zeolite membrane.     

钢轨交流闪光焊接过程过梁爆破特征分析

以高速摄影技术作为主要研究手段，研究钢轨交流闪光焊接过程过梁爆破特征，并结合热成像系统采集焊接过程温度场，以此为数据基础定量分析了钢轨交流闪光焊接过梁爆破特征. 结果表明,钢轨交流脉动闪光焊接工艺模式下，加速闪光阶段具有几个阶段中最高的闪光频次46.93次/s，脉动闪光阶段具有最低的闪光频次11.07次/s；连续闪光阶段闪光烈度为0.009 2 mm/次，是几个阶段中最强的，脉动阶段的闪光烈度最弱，为0.003 8 mm/次；从闪光加热因子来看，脉动阶段最高，符合了该阶段积累热量的主要目的；加速闪光阶段最低，是由于该阶段为了制造保护气氛产生的气化过梁带走了较多的热量；从闪光均匀度看，闪光最不均匀的阶段是闪平阶段，最均匀的阶段是脉动阶段，这恰恰说明了两待焊端面的微观平行情况在闪平阶段最差、脉动阶段最佳.     

近似完全匹配层边界条件吸收效果分析及衰减函数的改进

完全匹配层边界条件存在两个问题，一是如何减少实际应用带来的额外存储量以及提升计算速度，另一个是如何提升匹配层的吸收效果。对于第一个问题发展了多种非分裂形式，本文采用一种直接对波场进行变换的新型非分裂方法，相比卷积完全匹配层具有不改变方程的形式以及易于实现等优势。对于如何进一步提升完全匹配层吸收效果，没有太大的进展。这是因为离散差异使匹配层的吸收问题更为复杂，一般采取增加匹配层层数的措施缩小离散差，但是又会导致计算量和存储量的增加。本文以在不增加匹配层层数以及不减小理论误差的情况下减小离散差异所带来的虚假反射为目的，分析传统的衰减因子，研究匹配层的吸收机理，设计新的衰减因子，以提高完全匹配层的吸收性能。新衰减因子能够进一步削弱虚假反射振幅，在匹配层层数为5~20层时，对应的边界反射振幅只有改进前的40%~80%。     

不锈钢应力腐蚀开裂综述

应力腐蚀开裂一直以来是不锈钢领域的重要研究课题,也是许多行业亟需解决的工程问题。应力腐蚀开裂是材料、环境和应力三者相互作用的结果,由于其复杂性,目前人们对不锈钢发生应力腐蚀开裂的机理尚存在许多不同的见解,但是经过近一个世纪的研究,从材料选择、环境控制等方面入手,预防不锈钢发生应力腐蚀是能够达到的。综述了应力腐蚀开裂的特征、机理和三个影响因素(应力、材料和环境)。对应力腐蚀的阳极溶解机理和氢致开裂机理进行了概述,阐述并探讨了不锈钢应力腐蚀开裂的滑移溶解机理、氧化膜开裂机理以及氢致开裂机理。归纳了组织结构对不锈钢应力腐蚀的影响,分析了材料成分如(Ni、Mo和N)的添加与应力腐蚀敏感性的关系,总结了环境因素在应力腐蚀中的作用,对特定介质中不锈钢的应力腐蚀规律进行了归纳,并探讨了温度变化对不锈钢应力腐蚀的影响。介绍了近年来关于控制不锈钢应力腐蚀开裂方法的研究进展,如晶界工程、细化晶粒以及涂层等。最后展望了不锈钢应力腐蚀开裂未来的研究方向。     

氧化物陶瓷阻氚涂层的研究进展

利用阻氚涂层(TPB)降低结构材料中的氚损失,是聚变堆发展中的热点研究之一。陶瓷具有低氚渗透性、耐腐蚀性、高硬度和高热稳定性等特性,是目前聚变堆阻氚涂层首选材料。相对于硅化物、钛基等非氧化物陶瓷材料,氧化物陶瓷涂层具有熔点高、化学性质稳定、耐腐蚀性和阻氚渗透因子(PRF)高等优势,因此针对氧化物陶瓷阻氚涂层的研究较多。主要综述了单一氧化物陶瓷、复合氧化物陶瓷阻氚涂层近年来的研究现状与发展,如Y2O3、Er2O3、Al2O3等及其复合氧化物陶瓷材料,其中,因Al2O3及其复合物涂层具有优异的阻氚性能,得到了广泛的关注和研究。重点阐述了制备工艺、基体效应和辐照等影响氧化物陶瓷涂层阻氚性能的因素及氚在材料中的渗透机制,并分析了当前阻氚涂层在材料制备以及模拟服役环境等方面存在的不足与今后的研究重点,指出了未来可能的氧化物陶瓷阻氚涂层,以期为阻氚涂层的研究与后续实验提供一定的方向。     

TA18钛合金管材织构对环向拉伸性能的影响

利用织构增强原理,开发出了TA18(Ti-3Al-2.5V)钛合金860 MPa级高强度管材,保证了管材的工艺性能,同时又具有优异的力学服役性能。标准规定反映径向织构的管材收缩应变比(CSR)大于1.3,但对上限值未作规定。本研究设计出小管径的环向拉伸夹具,测试了不同CSR管材的环向拉伸力学性能,分析织构对环向抗拉强度的影响,发现存在一个最有利的CSR值为1.75,大于或小于该CSR值时都会导致管材环向屈服强度下降。进一步测定了对应管材的极图和ODF图,从微观结构上可以解释这一规律和本质。环向抗拉强度下降会引起液压系统工作时疲劳强度降低,CSR值的上限在工艺设计时应当加以控制。本研究对发展安全可靠的航空液压系统具有十分重要的理论意义和工程应用价值。     

Quantitative analysis of fuel-saving potential for waste heat recovery system integrated with hybrid electric vehicle

Hybrid electric vehicles (HEVs) with low fuel consumption, low emissions, and long driving range are the ideal transition models between conventional fuel vehicles and pure electric vehicles. The growing demand for increased vehicle efficiency has motivated the introduction of waste heat recovery (WHR) technology in the automotive industry, with the organic Rankine cycle (ORC) as the most promising measure for recycling waste energy. Currently, only a few studies have been conducted to couple HEV and WHR systems. These studies have mainly focused on the hybrid powertrain control strategy, but lack quantitative methods to comprehensively analyze the fuel-saving potential due to the WHR system. In this study, an HEV-WHR integrated system that includes a mechanism-based dynamic model of ORC and a hybrid diesel-electric truck model is established. Further, a quantitative evaluation method that simultaneously considers the negative integrated effects (increased vehicle weight and increased exhaust back pressure) and the positive impact values of the engine, motor, and WHR system on the fuel-saving potential is proposed. Finally, the influence of two environmental factors (wind speed and ambient temperature) on the fuel-saving performance is analyzed. The results reveal that under the standard highway driving cycle (HWY), the negative integrated effects reduce the ideal fuel-saving potential of the HEV-WHR system from 6.10% to 5.42%. However, the optimized performances of the engine, motor, and WHR system improve the fuel-saving rate by 0.39%, 1.81%, and 3.22%, respectively. The results also indicate that the fuel-saving potential increases from 1.62% to 8.60% with increasing wind speed and decreases from 6.70% to 4.25% with increasing ambient temperature.     

Enhanced heat transfer in rectangular duct with punched winglets

Thermal performance of a heat exchanger duct with punched winglets(PWs) mounted on the upper duct wall has been examined for Reynolds number(Re) ranging from 4100 to 25,500. In the present experiment, two types of PWs: punched delta-and elliptical-winglets(P-DW and P-EW) with four punched-hole sizes were tested at a fixed attack angle, optimal relative pitch and height. Also, data of solid delta-and elliptical-winglets(DW and EW) were included for comparison. The investigation has shown that the P-DW yields higher thermal-performance enhancement factor(η) than the P-EW. Although the solid DW and EW with no punch have the highest heat transfer and friction loss, the PWs yield better η than the solid ones. For PWs, the P-DW with smaller hole size has the peak heat transfer and friction loss around 5.7 and 40 times over the smooth duct, respectively but the optimum η of 2.17 is seen for the one with a certain hole size. The PWs provide η at about 5%–8% above the solid winglets.     

红石岩煤矿隐蔽致灾因素分析

为保障煤矿安全开采,有针对性地制定预防和治理措施,对红石岩煤矿隐蔽致灾因素进行探究。首先梳理了红石岩煤矿已揭露的地质情况和现有的钻探、物探和水质化验成果,瓦斯鉴定等资料,结合煤矿隐蔽致灾因素具有隐蔽性、时变性、突发性、难探测和难预防的特点,对其地面和井田内的采空区、废弃老窑,钻孔、地质构造、地下含水体、瓦斯和煤层自燃及煤层顶底板等因素进行了分析。总结出该矿主副井筒周边采空区水、因采动影响产生的顶底板导水裂隙带等主要隐蔽致灾因素,以及断层的活化和滞后出水及带出的有害气体等次要隐蔽致灾因素,并提出了相应的预防和治理措施。